输水渠道混凝土建筑裂缝修补聚脲材料制备及性能
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福建水利电力职业技术学院建筑工程学院,福建 永安 366000

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福建省教育厅科技项目(JZ180470)。


Preparation and Properties of Polyurea Material for Repairing Cracks in Concrete Buildings in Water Conveyance Channels
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School of Architecture and Engineering, Fujian Polytechnic of Water Conservancy and Electric Power, Yong'an 366000, Fujian, China

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    摘要:

    为制备高性能的聚脲修补材料,验证聚脲材料的防水性能,研究输水渠道混凝土建筑裂缝修补聚脲材料制备及性能。脱水处理多元醇和异氰酸酯(MDI-50)并将二者混合获得A组分,混合4,4’-双仲丁氨基二苯甲烷(MBDA)和助剂等材料获得B组分,混合A组分和B组分得到输水渠道混凝土建筑裂缝修补聚脲材料,通过异氰酸酯基(NCO)检测确定最佳反应温度与反应温度,分析聚脲修复后混凝土的力学性能和抗水压冲击性能。结果表明:随着反应时间的延长,聚脲材料中的NCO质量分数展现出先递减后趋于稳定的趋势,其中3h为最优反应时长;当反应温度逐渐升高时,NCO质量分数呈现下降趋势,在85 ℃条件下的异氰酸酯反应最为理想。综合上述结果可知,聚脲材料在修复混凝土裂缝方面成效显著,能有效维持并提升混凝土的抗压强度与极限应变性能;针对较宽的裂缝,选择合适的涂覆厚度至关重要,其中,涂覆厚度为4和6 mm时,修复效果更为优异。

    Abstract:

    In order to prepare high performance polyurea repairing material and verify the waterproof performance of polyurea material, the preparation and performance of polyurea repairing material for concrete building cracks in water transmission channels were studied. A component was obtained by mixing dehydrated water polyol and isocyanate, B component was obtained by mixing 4,4 ''-bis-butylaminobenzene methane and additives, and polyurea material was obtained by mixing A and B components to repair cracks in concrete buildings in water conveyance channels. The optimal reaction temperature and reaction temperature were determined by isocyanate group (NCO) detection. The mechanical properties and hydrostatic impact resistance of concrete repaired with polyurea were analyzed. The experimental results showed that with the extension of reaction time, the NCO mass fraction in the polyurea material exhibited a decreasing trend and then tended to stabilize, with 3 h being the optimal reaction time. As the reaction temperature gradually increases, the mass fraction of NCO shows a decreasing trend, and the reaction of isocyanates is most ideal at 85 ℃. Based on the above results, it can be concluded that polyurea materials have significant effects in repairing concrete cracks, effectively maintaining and improving the compressive strength and ultimate strain performance of concrete. Choosing the appropriate coating thickness is crucial for wider cracks, among which the repair effect is more excellent when the coating thickness is 4 and 6 mm.

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祝磊.输水渠道混凝土建筑裂缝修补聚脲材料制备及性能[J].西昌学院学报(自然科学版),2025,39(2):66-75.

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  • 收稿日期:2025-02-10
  • 最后修改日期:2025-06-13
  • 录用日期:2025-03-31
  • 在线发布日期: 2025-07-10
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